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Aqueous Flow Organic Battery for Grid-Scale Energy Storage Developed

Posted on the 27 June 2014 by Dailyfusion @dailyfusion
Sri Narayan focuses on the fundamental and applied aspects of electrochemical energy conversionSri Narayan focuses on the fundamental and applied aspects of electrochemical energy conversion. (Credit: USC / Gus Ruelas)

Researchers at the University of Southern California (USC) have created an inexpensive aqueous flow organic battery for grid-scale energy storage. The new battery contains no metals or toxic materials.

“The batteries last for about 5,000 recharge cycles, giving them an estimated 15-year life span,” said Sri Narayan, professor of chemistry at the USC Dornsife College of Letters, Arts and Sciences and corresponding author of a paper describing the new batteries that was published online by the Journal of the Electrochemical Society on June 20 (see footnote). “Lithium ion batteries degrade after around 1,000 cycles and cost 10 times more to manufacture.” Narayan collaborated with G.K. Surya Prakash, professor of chemistry and director of the USC Loker Hydrocarbon Research Institute, as well as USC’s Bo Yang, Lena Hoober-Burkhardt and Fang Wang. “Such organic flow batteries will be game-changers for grid electrical energy storage in terms of simplicity, cost, reliability and sustainability,” Prakash said.

SEE ALSO: New Organic Flow Battery May Revolutionize Energy Storage

Schematic of aqueous organic redox flow battery

Schematic of aqueous organic redox flow battery. (Credit: See citation at the end of this article)

The batteries could pave the way for renewable energy sources to make up a greater share of the nation’s energy generation. Solar panels can only generate power when the sun’s shining, and wind turbines can only generate power when the wind blows. That inherent unreliability makes it difficult for power companies to rely on them to meet customer demand. With batteries to store surplus energy, which can be doled out as needed, that sporadic unreliability could cease to be an issue. “ ‘Mega-scale’ energy storage is a critical problem in the future of renewable energy,” Narayan said. The new battery is based on a redox flow design—similar in design to a fuel cell, with two tanks of electroactive materials dissolved in water. The solutions are pumped into a cell containing a membrane between the two fluids with electrodes on either side releasing energy. The design has the advantage of decoupling power from energy. The tanks of electroactive materials can be made as large as needed—increasing the total amount of energy the system can store—or the central cell can be tweaked to release that energy faster or slower, altering the amount of power (energy released over time) that the system can generate.

The team’s breakthrough centered on the electroactive materials. While previous battery designs have used metals or toxic chemicals, Narayan and Prakash wanted to find an organic compound that could be dissolved in water. Such a system would create a minimal impact on the environment and would likely be cheap, they figured. Through a combination of molecule design and trial-and-error, the scientists found that certain naturally occurring quinones—oxidized organic compounds—fit the bill. Quinones are found in plants, fungi, bacteria and some animals, and are involved in photosynthesis and cellular respiration. “These are the types of molecules that nature uses for energy transfer,” Narayan said. Currently, the quinones needed for the batteries are manufactured from naturally occurring hydrocarbons. In the future, the potential exists to derive them from carbon dioxide, Narayan said. The team has filed several patents in regards to design of the aqueous flow battery and next plans to build a larger scale version. The research was funded by the ARPA-E Open-Funding Opportunity Announcement program (grant number DE-AR0000337), USC and the Loker Hydrocarbon Research Institute.

Yang, B., Hoober-Burkhardt, L., Wang, F., Surya Prakash, G., & Narayanan, S. (2014). An Inexpensive Aqueous Flow Battery for Large-Scale Electrical Energy Storage Based on Water-Soluble Organic Redox Couples Journal of the Electrochemical Society, 161 (9) DOI: 10.1149/2.1001409jes

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